Synthesis, crystal structures and spectroscopy studies of Mo(IV) complexes synthesized in reactions with kojic acid, maltol and ethylmaltol

2012
journal article
article
cris.lastimport.wos2024-04-10T02:21:29Z
dc.abstract.enIn the reaction of maltol and its derivatives with a Mo(IV) cyano complex, three new salts were isolated and characterized by physicochemical measurements. The X-ray single crystal measurements of two salts of the formula $(PPh_{4})_{4}[Mo(CN)_{3}O(LL)]\cdot3H_{2}O$, where LL = maltol or ethylmaltol, show a distorted octahe- dral geometry of the anions. The steric hindrance introduced by the ethyl group changes mainly the inter- molecular distances in the solid state and the network of hydrogen bonds. All the synthesized salts were compared and discussed with the family of NO, NN and OO donating $[Mo(CN)_{3}O(LL)]^{n-}$ groups. The role of the ligand protonation constant on the isolation of the products is presented by the synthesis of a $(PPh_{4})_{2}[Mo(CN)_{4}O(H_{2}O)]\cdot5H_{2}O$ salt.pl
dc.affiliationWydział Chemii : Zakład Krystalochemii i Krystalofizykipl
dc.affiliationWydział Chemii : Zakład Chemii Nieorganicznejpl
dc.contributor.authorSzklarzewicz, Janusz - 132237 pl
dc.contributor.authorPaciorek, Patrycja - 156411 pl
dc.contributor.authorZabierowski, Piotr - 107039 pl
dc.contributor.authorKurpiewska, Katarzyna - 142859 pl
dc.contributor.authorMikuriya, Masahiropl
dc.contributor.authorYoshioka, Daisukepl
dc.date.accessioned2015-09-04T07:22:29Z
dc.date.available2015-09-04T07:22:29Z
dc.date.issued2012pl
dc.description.number1pl
dc.description.physical35-41pl
dc.description.points30pl
dc.description.volume37pl
dc.identifier.doi10.1016/j.poly.2012.01.033pl
dc.identifier.eissn1873-3719pl
dc.identifier.issn0277-5387pl
dc.identifier.urihttp://ruj.uj.edu.pl/xmlui/handle/item/15340
dc.languageengpl
dc.language.containerengpl
dc.rightsDodaję tylko opis bibliograficzny*
dc.rights.licencebez licencji
dc.rights.uri*
dc.subject.enkojic acidpl
dc.subject.enethylmaltolpl
dc.subject.enmaltolpl
dc.subject.enmolybdenumpl
dc.subject.encyano complexespl
dc.subtypeArticlepl
dc.titleSynthesis, crystal structures and spectroscopy studies of Mo(IV) complexes synthesized in reactions with kojic acid, maltol and ethylmaltolpl
dc.title.journalPolyhedronpl
dc.typeJournalArticlepl
dspace.entity.typePublication
cris.lastimport.wos
2024-04-10T02:21:29Z
dc.abstract.enpl
In the reaction of maltol and its derivatives with a Mo(IV) cyano complex, three new salts were isolated and characterized by physicochemical measurements. The X-ray single crystal measurements of two salts of the formula $(PPh_{4})_{4}[Mo(CN)_{3}O(LL)]\cdot3H_{2}O$, where LL = maltol or ethylmaltol, show a distorted octahe- dral geometry of the anions. The steric hindrance introduced by the ethyl group changes mainly the inter- molecular distances in the solid state and the network of hydrogen bonds. All the synthesized salts were compared and discussed with the family of NO, NN and OO donating $[Mo(CN)_{3}O(LL)]^{n-}$ groups. The role of the ligand protonation constant on the isolation of the products is presented by the synthesis of a $(PPh_{4})_{2}[Mo(CN)_{4}O(H_{2}O)]\cdot5H_{2}O$ salt.
dc.affiliationpl
Wydział Chemii : Zakład Krystalochemii i Krystalofizyki
dc.affiliationpl
Wydział Chemii : Zakład Chemii Nieorganicznej
dc.contributor.authorpl
Szklarzewicz, Janusz - 132237
dc.contributor.authorpl
Paciorek, Patrycja - 156411
dc.contributor.authorpl
Zabierowski, Piotr - 107039
dc.contributor.authorpl
Kurpiewska, Katarzyna - 142859
dc.contributor.authorpl
Mikuriya, Masahiro
dc.contributor.authorpl
Yoshioka, Daisuke
dc.date.accessioned
2015-09-04T07:22:29Z
dc.date.available
2015-09-04T07:22:29Z
dc.date.issuedpl
2012
dc.description.numberpl
1
dc.description.physicalpl
35-41
dc.description.pointspl
30
dc.description.volumepl
37
dc.identifier.doipl
10.1016/j.poly.2012.01.033
dc.identifier.eissnpl
1873-3719
dc.identifier.issnpl
0277-5387
dc.identifier.uri
http://ruj.uj.edu.pl/xmlui/handle/item/15340
dc.languagepl
eng
dc.language.containerpl
eng
dc.rights*
Dodaję tylko opis bibliograficzny
dc.rights.licence
bez licencji
dc.rights.uri*
dc.subject.enpl
kojic acid
dc.subject.enpl
ethylmaltol
dc.subject.enpl
maltol
dc.subject.enpl
molybdenum
dc.subject.enpl
cyano complexes
dc.subtypepl
Article
dc.titlepl
Synthesis, crystal structures and spectroscopy studies of Mo(IV) complexes synthesized in reactions with kojic acid, maltol and ethylmaltol
dc.title.journalpl
Polyhedron
dc.typepl
JournalArticle
dspace.entity.type
Publication

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