Effect of cobalt doping on the dielectric response of ceramics

2014
journal article
article
14
cris.lastimport.wos2024-04-09T19:13:26Z
dc.abstract.enDielectric response of Ba 0.95 Pb 0.05 TiO 3 ceramics doped with 0.1 and 1 wt.% of Co 2 O 3 , synthesized by conven- tional high-temperature method, wa s studied in wide temperature and frequency range. The temperature dependences of the real and the imaginary parts of dielectric permittivity of the ceramics were compared with those of BaTiO 3 and Ba 0.95 Pb 0.05 TiO 3. The addition of Co 3+ ions results in a broadening of dielectric anom- alies related to the transition to p araelectric cubic phase, and the structural transition between the tetragonal and the orthorhombic phases. At low temperatures (125 – 200 K) the dielectric absorp- tion of Co-doped Ba 0.95 Pb 0.05 TiO 3 ceramics was found to exhibit relaxor-like properties. The die lectric response has been found to contain the contributions characte ristic of fluctuations of the polar nanoregion boundaries and reorientations of the dipole moments between allowed directions in the nanoregions in the rhombohe- dral and the orthorhombic phases. The behavior speaks in favor of ordering of polar defects in the host lattice of Ba 0.95 Pb 0.05 TiO 3 in a form polar nanoregions.pl
dc.affiliationWydział Chemii : Zakład Technologii Chemicznejpl
dc.contributor.authorMarkiewicz, E.pl
dc.contributor.authorBujakiewicz-Korońska, Renatapl
dc.contributor.authorMajda, Dorota - 130211 pl
dc.contributor.authorVasylechko, Leonidpl
dc.contributor.authorKalvane, Annapl
dc.contributor.authorMatczak, M.pl
dc.date.accession2019-02-15pl
dc.date.accessioned2015-06-17T08:33:58Z
dc.date.available2015-06-17T08:33:58Z
dc.date.issued2014pl
dc.date.openaccess0
dc.description.accesstimew momencie opublikowania
dc.description.number1pl
dc.description.physical92-101pl
dc.description.versionostateczna wersja wydawcy
dc.description.volume32pl
dc.identifier.doi10.1007/s10832-013-9865-1pl
dc.identifier.eissn1573-8663pl
dc.identifier.issn1385-3449pl
dc.identifier.projectROD UJ / Ppl
dc.identifier.urihttp://ruj.uj.edu.pl/xmlui/handle/item/9673
dc.identifier.weblinkhttps://link.springer.com/content/pdf/10.1007%2Fs10832-013-9865-1.pdfpl
dc.languageengpl
dc.language.containerengpl
dc.rightsUdzielam licencji. Uznanie autorstwa 4.0 Międzynarodowa*
dc.rights.licenceCC-BY
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/legalcode.pl*
dc.share.typeinne
dc.subject.en$B_{0.95}Pb_{0.05}TiO_3$pl
dc.subject.enco-dopingpl
dc.subject.endeviation from the Curie-Weisslawpl
dc.subject.endielectric propertiespl
dc.subtypeArticlepl
dc.titleEffect of cobalt doping on the dielectric response of $B_{0.95}Pb_{0.05}TiO_3$ ceramicspl
dc.title.journalJournal of Electroceramicspl
dc.typeJournalArticlepl
dspace.entity.typePublication
cris.lastimport.wos
2024-04-09T19:13:26Z
dc.abstract.enpl
Dielectric response of Ba 0.95 Pb 0.05 TiO 3 ceramics doped with 0.1 and 1 wt.% of Co 2 O 3 , synthesized by conven- tional high-temperature method, wa s studied in wide temperature and frequency range. The temperature dependences of the real and the imaginary parts of dielectric permittivity of the ceramics were compared with those of BaTiO 3 and Ba 0.95 Pb 0.05 TiO 3. The addition of Co 3+ ions results in a broadening of dielectric anom- alies related to the transition to p araelectric cubic phase, and the structural transition between the tetragonal and the orthorhombic phases. At low temperatures (125 – 200 K) the dielectric absorp- tion of Co-doped Ba 0.95 Pb 0.05 TiO 3 ceramics was found to exhibit relaxor-like properties. The die lectric response has been found to contain the contributions characte ristic of fluctuations of the polar nanoregion boundaries and reorientations of the dipole moments between allowed directions in the nanoregions in the rhombohe- dral and the orthorhombic phases. The behavior speaks in favor of ordering of polar defects in the host lattice of Ba 0.95 Pb 0.05 TiO 3 in a form polar nanoregions.
dc.affiliationpl
Wydział Chemii : Zakład Technologii Chemicznej
dc.contributor.authorpl
Markiewicz, E.
dc.contributor.authorpl
Bujakiewicz-Korońska, Renata
dc.contributor.authorpl
Majda, Dorota - 130211
dc.contributor.authorpl
Vasylechko, Leonid
dc.contributor.authorpl
Kalvane, Anna
dc.contributor.authorpl
Matczak, M.
dc.date.accessionpl
2019-02-15
dc.date.accessioned
2015-06-17T08:33:58Z
dc.date.available
2015-06-17T08:33:58Z
dc.date.issuedpl
2014
dc.date.openaccess
0
dc.description.accesstime
w momencie opublikowania
dc.description.numberpl
1
dc.description.physicalpl
92-101
dc.description.version
ostateczna wersja wydawcy
dc.description.volumepl
32
dc.identifier.doipl
10.1007/s10832-013-9865-1
dc.identifier.eissnpl
1573-8663
dc.identifier.issnpl
1385-3449
dc.identifier.projectpl
ROD UJ / P
dc.identifier.uri
http://ruj.uj.edu.pl/xmlui/handle/item/9673
dc.identifier.weblinkpl
https://link.springer.com/content/pdf/10.1007%2Fs10832-013-9865-1.pdf
dc.languagepl
eng
dc.language.containerpl
eng
dc.rights*
Udzielam licencji. Uznanie autorstwa 4.0 Międzynarodowa
dc.rights.licence
CC-BY
dc.rights.uri*
http://creativecommons.org/licenses/by/4.0/legalcode.pl
dc.share.type
inne
dc.subject.enpl
$B_{0.95}Pb_{0.05}TiO_3$
dc.subject.enpl
co-doping
dc.subject.enpl
deviation from the Curie-Weisslaw
dc.subject.enpl
dielectric properties
dc.subtypepl
Article
dc.titlepl
Effect of cobalt doping on the dielectric response of $B_{0.95}Pb_{0.05}TiO_3$ ceramics
dc.title.journalpl
Journal of Electroceramics
dc.typepl
JournalArticle
dspace.entity.type
Publication
Affiliations

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