UV and visible light active aqueous titanium dioxide colloids stabilized by surfactants

2014
journal article
article
15
cris.lastimport.wos2024-04-09T21:47:56Z
dc.abstract.enAttempts to increase the stability of photocatalytically active nanodispersions of titanium dioxide over a wide range of pH (3 – 10) were undertaken. Polyethylene glycols (PEGs) with di ff erent molecular weights and polyoxyethylenesorbitan monooleate (Tween® 80) were tested as stabilizing agents of TiO 2 nano- particles. The results of DLS measurements proved the stabilizing e ff ect of Tween® 80 while the systems involving PEGs, independently of the polymer concentration, showed a tendency to form aggregates in neutral solutions. The colloids stabilized with Tween® 80 were photosensitized with 2,3-naphthalenediol (nd) or 2-hydroxy-3-naphthoic acid (hn) or catechol (cat). The photocatalytic activity of such colloids has been assessed in an azure B degradation reaction using both UV and visible light. The nd@TiO 2 + Tween colloid appeared particularly photoactive upon visible light irradiation. Moreover, the comparison of activi- ties of nd@TiO 2 + Tween and TiO 2 + Tween revealed a signi fi cantly better performance of the former nanodispersion, independently of the irradiation conditions (UV or visible light). This e ff ect has been explained by di ff erent structures of micelles formed in the case of TiO 2 and nd@TiO 2 stabilized with Tween® 80.pl
dc.affiliationWydział Chemii : Zakład Chemii Nieorganicznejpl
dc.contributor.authorPacia, Michał - 155739 pl
dc.contributor.authorWarszyński, Piotrpl
dc.contributor.authorMacyk, Wojciech - 130162 pl
dc.date.accessioned2015-06-12T10:19:21Z
dc.date.available2015-06-12T10:19:21Z
dc.date.issued2014pl
dc.description.number33pl
dc.description.physical12480-12485pl
dc.description.volume43pl
dc.identifier.doi10.1039/c4dt00285gpl
dc.identifier.eissn1477-9234pl
dc.identifier.issn1477-9226pl
dc.identifier.urihttp://ruj.uj.edu.pl/xmlui/handle/item/9512
dc.languageengpl
dc.language.containerengpl
dc.rights.licencebez licencji
dc.subtypeArticlepl
dc.titleUV and visible light active aqueous titanium dioxide colloids stabilized by surfactantspl
dc.title.journalDalton Transactionspl
dc.typeJournalArticlepl
dspace.entity.typePublication
cris.lastimport.wos
2024-04-09T21:47:56Z
dc.abstract.enpl
Attempts to increase the stability of photocatalytically active nanodispersions of titanium dioxide over a wide range of pH (3 – 10) were undertaken. Polyethylene glycols (PEGs) with di ff erent molecular weights and polyoxyethylenesorbitan monooleate (Tween® 80) were tested as stabilizing agents of TiO 2 nano- particles. The results of DLS measurements proved the stabilizing e ff ect of Tween® 80 while the systems involving PEGs, independently of the polymer concentration, showed a tendency to form aggregates in neutral solutions. The colloids stabilized with Tween® 80 were photosensitized with 2,3-naphthalenediol (nd) or 2-hydroxy-3-naphthoic acid (hn) or catechol (cat). The photocatalytic activity of such colloids has been assessed in an azure B degradation reaction using both UV and visible light. The nd@TiO 2 + Tween colloid appeared particularly photoactive upon visible light irradiation. Moreover, the comparison of activi- ties of nd@TiO 2 + Tween and TiO 2 + Tween revealed a signi fi cantly better performance of the former nanodispersion, independently of the irradiation conditions (UV or visible light). This e ff ect has been explained by di ff erent structures of micelles formed in the case of TiO 2 and nd@TiO 2 stabilized with Tween® 80.
dc.affiliationpl
Wydział Chemii : Zakład Chemii Nieorganicznej
dc.contributor.authorpl
Pacia, Michał - 155739
dc.contributor.authorpl
Warszyński, Piotr
dc.contributor.authorpl
Macyk, Wojciech - 130162
dc.date.accessioned
2015-06-12T10:19:21Z
dc.date.available
2015-06-12T10:19:21Z
dc.date.issuedpl
2014
dc.description.numberpl
33
dc.description.physicalpl
12480-12485
dc.description.volumepl
43
dc.identifier.doipl
10.1039/c4dt00285g
dc.identifier.eissnpl
1477-9234
dc.identifier.issnpl
1477-9226
dc.identifier.uri
http://ruj.uj.edu.pl/xmlui/handle/item/9512
dc.languagepl
eng
dc.language.containerpl
eng
dc.rights.licence
bez licencji
dc.subtypepl
Article
dc.titlepl
UV and visible light active aqueous titanium dioxide colloids stabilized by surfactants
dc.title.journalpl
Dalton Transactions
dc.typepl
JournalArticle
dspace.entity.type
Publication

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