Simple view
Full metadata view
Authors
Statistics
UV and visible light active aqueous titanium dioxide colloids stabilized by surfactants
Attempts to increase the stability of photocatalytically active nanodispersions of titanium dioxide over a wide range of pH (3 – 10) were undertaken. Polyethylene glycols (PEGs) with di ff erent molecular weights and polyoxyethylenesorbitan monooleate (Tween® 80) were tested as stabilizing agents of TiO 2 nano- particles. The results of DLS measurements proved the stabilizing e ff ect of Tween® 80 while the systems involving PEGs, independently of the polymer concentration, showed a tendency to form aggregates in neutral solutions. The colloids stabilized with Tween® 80 were photosensitized with 2,3-naphthalenediol (nd) or 2-hydroxy-3-naphthoic acid (hn) or catechol (cat). The photocatalytic activity of such colloids has been assessed in an azure B degradation reaction using both UV and visible light. The nd@TiO 2
- Tween colloid appeared particularly photoactive upon visible light irradiation. Moreover, the comparison of activi- ties of nd@TiO 2
- Tween and TiO 2
- Tween revealed a signi fi cantly better performance of the former nanodispersion, independently of the irradiation conditions (UV or visible light). This e ff ect has been explained by di ff erent structures of micelles formed in the case of TiO 2 and nd@TiO 2 stabilized with Tween® 80.
cris.lastimport.wos | 2024-04-09T21:47:56Z | |
dc.abstract.en | Attempts to increase the stability of photocatalytically active nanodispersions of titanium dioxide over a wide range of pH (3 – 10) were undertaken. Polyethylene glycols (PEGs) with di ff erent molecular weights and polyoxyethylenesorbitan monooleate (Tween® 80) were tested as stabilizing agents of TiO 2 nano- particles. The results of DLS measurements proved the stabilizing e ff ect of Tween® 80 while the systems involving PEGs, independently of the polymer concentration, showed a tendency to form aggregates in neutral solutions. The colloids stabilized with Tween® 80 were photosensitized with 2,3-naphthalenediol (nd) or 2-hydroxy-3-naphthoic acid (hn) or catechol (cat). The photocatalytic activity of such colloids has been assessed in an azure B degradation reaction using both UV and visible light. The nd@TiO 2 + Tween colloid appeared particularly photoactive upon visible light irradiation. Moreover, the comparison of activi- ties of nd@TiO 2 + Tween and TiO 2 + Tween revealed a signi fi cantly better performance of the former nanodispersion, independently of the irradiation conditions (UV or visible light). This e ff ect has been explained by di ff erent structures of micelles formed in the case of TiO 2 and nd@TiO 2 stabilized with Tween® 80. | pl |
dc.affiliation | Wydział Chemii : Zakład Chemii Nieorganicznej | pl |
dc.contributor.author | Pacia, Michał - 155739 | pl |
dc.contributor.author | Warszyński, Piotr | pl |
dc.contributor.author | Macyk, Wojciech - 130162 | pl |
dc.date.accessioned | 2015-06-12T10:19:21Z | |
dc.date.available | 2015-06-12T10:19:21Z | |
dc.date.issued | 2014 | pl |
dc.description.number | 33 | pl |
dc.description.physical | 12480-12485 | pl |
dc.description.volume | 43 | pl |
dc.identifier.doi | 10.1039/c4dt00285g | pl |
dc.identifier.eissn | 1477-9234 | pl |
dc.identifier.issn | 1477-9226 | pl |
dc.identifier.uri | http://ruj.uj.edu.pl/xmlui/handle/item/9512 | |
dc.language | eng | pl |
dc.language.container | eng | pl |
dc.rights.licence | bez licencji | |
dc.subtype | Article | pl |
dc.title | UV and visible light active aqueous titanium dioxide colloids stabilized by surfactants | pl |
dc.title.journal | Dalton Transactions | pl |
dc.type | JournalArticle | pl |
dspace.entity.type | Publication |