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Selective catalytic oxidation (SCO) of ammonia to nitrogen over hydrotalcite originated Mg-Cu-Fe mixed metal oxides
hydrotalcite-like materials
selective catalytic oxidation of ammonia
reaction mechanism
Bibliogr. s. 1353-1354.
Mg-Cu-Fe oxide systems, obtained from hydrotalcite-like precursors, were tested as catalysts for the selective catalytic oxidation (SCO) of ammonia. Copper containing catalysts were active in low-temperature SCO processes; however, their selectivity to nitrogen significantly decreased at higher temperatures. The optimum composition of the catalyst to guarantee high activity and selectivity to N2 was proposed. Temperature-programmed experiments, SCO catalytic tests performed with various contact times and additional tests on the samples in the selective catalytic reduction of NO with ammonia showed that the SCO process over the studied calcined hydrotalcites proceeds according to the internal SCR mechanism and oxidation of ammonia to NO is a rate-determining step in the low-temperature range.
cris.lastimport.wos | 2024-04-09T20:15:36Z | |
dc.abstract.en | Mg-Cu-Fe oxide systems, obtained from hydrotalcite-like precursors, were tested as catalysts for the selective catalytic oxidation (SCO) of ammonia. Copper containing catalysts were active in low-temperature SCO processes; however, their selectivity to nitrogen significantly decreased at higher temperatures. The optimum composition of the catalyst to guarantee high activity and selectivity to N2 was proposed. Temperature-programmed experiments, SCO catalytic tests performed with various contact times and additional tests on the samples in the selective catalytic reduction of NO with ammonia showed that the SCO process over the studied calcined hydrotalcites proceeds according to the internal SCR mechanism and oxidation of ammonia to NO is a rate-determining step in the low-temperature range. | pl |
dc.affiliation | Wydział Biologii i Nauk o Ziemi : Instytut Nauk Geologicznych | pl |
dc.affiliation | Wydział Chemii : Zakład Chemii Nieorganicznej | pl |
dc.affiliation | Wydział Chemii : Zakład Technologii Chemicznej | pl |
dc.contributor.author | Chmielarz, Lucjan - 127527 | pl |
dc.contributor.author | Węgrzyn, Agnieszka - 132595 | pl |
dc.contributor.author | Wojciechowska, Magdalena | pl |
dc.contributor.author | Witkowski, Stefan - 132669 | pl |
dc.contributor.author | Michalik, Marek - 130514 | pl |
dc.date.accession | 2019-03-26 | pl |
dc.date.accessioned | 2019-03-26T09:15:45Z | |
dc.date.available | 2019-03-26T09:15:45Z | |
dc.date.issued | 2011 | pl |
dc.date.openaccess | 0 | |
dc.description.accesstime | w momencie opublikowania | |
dc.description.additional | Bibliogr. s. 1353-1354. | pl |
dc.description.number | 9 | pl |
dc.description.physical | 1345-1354 | pl |
dc.description.version | ostateczna wersja wydawcy | |
dc.description.volume | 141 | pl |
dc.identifier.doi | 10.1007/s10562-011-0653-8 | pl |
dc.identifier.eissn | 1572-879X | pl |
dc.identifier.issn | 1011-372X | pl |
dc.identifier.project | ROD UJ / OP | pl |
dc.identifier.uri | https://ruj.uj.edu.pl/xmlui/handle/item/71386 | |
dc.identifier.weblink | https://link.springer.com/content/pdf/10.1007%2Fs10562-011-0653-8.pdf | pl |
dc.language | eng | pl |
dc.language.container | eng | pl |
dc.rights | Udzielam licencji. Uznanie autorstwa - Użycie niekomercyjne | * |
dc.rights.licence | CC-BY-NC | |
dc.rights.uri | http://creativecommons.org/licenses | * |
dc.share.type | inne | |
dc.subject.en | hydrotalcite-like materials | pl |
dc.subject.en | selective catalytic oxidation of ammonia | pl |
dc.subject.en | reaction mechanism | pl |
dc.subtype | Article | pl |
dc.title | Selective catalytic oxidation (SCO) of ammonia to nitrogen over hydrotalcite originated Mg-Cu-Fe mixed metal oxides | pl |
dc.title.journal | Catalysis Letters | pl |
dc.type | JournalArticle | pl |
dspace.entity.type | Publication |
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