Selective catalytic oxidation (SCO) of ammonia to nitrogen over hydrotalcite originated Mg-Cu-Fe mixed metal oxides

2011
journal article
article
71
cris.lastimport.wos2024-04-09T20:15:36Z
dc.abstract.enMg-Cu-Fe oxide systems, obtained from hydrotalcite-like precursors, were tested as catalysts for the selective catalytic oxidation (SCO) of ammonia. Copper containing catalysts were active in low-temperature SCO processes; however, their selectivity to nitrogen significantly decreased at higher temperatures. The optimum composition of the catalyst to guarantee high activity and selectivity to N2 was proposed. Temperature-programmed experiments, SCO catalytic tests performed with various contact times and additional tests on the samples in the selective catalytic reduction of NO with ammonia showed that the SCO process over the studied calcined hydrotalcites proceeds according to the internal SCR mechanism and oxidation of ammonia to NO is a rate-determining step in the low-temperature range.pl
dc.affiliationWydział Biologii i Nauk o Ziemi : Instytut Nauk Geologicznychpl
dc.affiliationWydział Chemii : Zakład Chemii Nieorganicznejpl
dc.affiliationWydział Chemii : Zakład Technologii Chemicznejpl
dc.contributor.authorChmielarz, Lucjan - 127527 pl
dc.contributor.authorWęgrzyn, Agnieszka - 132595 pl
dc.contributor.authorWojciechowska, Magdalenapl
dc.contributor.authorWitkowski, Stefan - 132669 pl
dc.contributor.authorMichalik, Marek - 130514 pl
dc.date.accession2019-03-26pl
dc.date.accessioned2019-03-26T09:15:45Z
dc.date.available2019-03-26T09:15:45Z
dc.date.issued2011pl
dc.date.openaccess0
dc.description.accesstimew momencie opublikowania
dc.description.additionalBibliogr. s. 1353-1354.pl
dc.description.number9pl
dc.description.physical1345-1354pl
dc.description.versionostateczna wersja wydawcy
dc.description.volume141pl
dc.identifier.doi10.1007/s10562-011-0653-8pl
dc.identifier.eissn1572-879Xpl
dc.identifier.issn1011-372Xpl
dc.identifier.projectROD UJ / OPpl
dc.identifier.urihttps://ruj.uj.edu.pl/xmlui/handle/item/71386
dc.identifier.weblinkhttps://link.springer.com/content/pdf/10.1007%2Fs10562-011-0653-8.pdfpl
dc.languageengpl
dc.language.containerengpl
dc.rightsUdzielam licencji. Uznanie autorstwa - Użycie niekomercyjne*
dc.rights.licenceCC-BY-NC
dc.rights.urihttp://creativecommons.org/licenses*
dc.share.typeinne
dc.subject.enhydrotalcite-like materialspl
dc.subject.enselective catalytic oxidation of ammoniapl
dc.subject.enreaction mechanismpl
dc.subtypeArticlepl
dc.titleSelective catalytic oxidation (SCO) of ammonia to nitrogen over hydrotalcite originated Mg-Cu-Fe mixed metal oxidespl
dc.title.journalCatalysis Letterspl
dc.typeJournalArticlepl
dspace.entity.typePublication
cris.lastimport.wos
2024-04-09T20:15:36Z
dc.abstract.enpl
Mg-Cu-Fe oxide systems, obtained from hydrotalcite-like precursors, were tested as catalysts for the selective catalytic oxidation (SCO) of ammonia. Copper containing catalysts were active in low-temperature SCO processes; however, their selectivity to nitrogen significantly decreased at higher temperatures. The optimum composition of the catalyst to guarantee high activity and selectivity to N2 was proposed. Temperature-programmed experiments, SCO catalytic tests performed with various contact times and additional tests on the samples in the selective catalytic reduction of NO with ammonia showed that the SCO process over the studied calcined hydrotalcites proceeds according to the internal SCR mechanism and oxidation of ammonia to NO is a rate-determining step in the low-temperature range.
dc.affiliationpl
Wydział Biologii i Nauk o Ziemi : Instytut Nauk Geologicznych
dc.affiliationpl
Wydział Chemii : Zakład Chemii Nieorganicznej
dc.affiliationpl
Wydział Chemii : Zakład Technologii Chemicznej
dc.contributor.authorpl
Chmielarz, Lucjan - 127527
dc.contributor.authorpl
Węgrzyn, Agnieszka - 132595
dc.contributor.authorpl
Wojciechowska, Magdalena
dc.contributor.authorpl
Witkowski, Stefan - 132669
dc.contributor.authorpl
Michalik, Marek - 130514
dc.date.accessionpl
2019-03-26
dc.date.accessioned
2019-03-26T09:15:45Z
dc.date.available
2019-03-26T09:15:45Z
dc.date.issuedpl
2011
dc.date.openaccess
0
dc.description.accesstime
w momencie opublikowania
dc.description.additionalpl
Bibliogr. s. 1353-1354.
dc.description.numberpl
9
dc.description.physicalpl
1345-1354
dc.description.version
ostateczna wersja wydawcy
dc.description.volumepl
141
dc.identifier.doipl
10.1007/s10562-011-0653-8
dc.identifier.eissnpl
1572-879X
dc.identifier.issnpl
1011-372X
dc.identifier.projectpl
ROD UJ / OP
dc.identifier.uri
https://ruj.uj.edu.pl/xmlui/handle/item/71386
dc.identifier.weblinkpl
https://link.springer.com/content/pdf/10.1007%2Fs10562-011-0653-8.pdf
dc.languagepl
eng
dc.language.containerpl
eng
dc.rights*
Udzielam licencji. Uznanie autorstwa - Użycie niekomercyjne
dc.rights.licence
CC-BY-NC
dc.rights.uri*
http://creativecommons.org/licenses
dc.share.type
inne
dc.subject.enpl
hydrotalcite-like materials
dc.subject.enpl
selective catalytic oxidation of ammonia
dc.subject.enpl
reaction mechanism
dc.subtypepl
Article
dc.titlepl
Selective catalytic oxidation (SCO) of ammonia to nitrogen over hydrotalcite originated Mg-Cu-Fe mixed metal oxides
dc.title.journalpl
Catalysis Letters
dc.typepl
JournalArticle
dspace.entity.type
Publication
Affiliations

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