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On-surface synthesis and intermolecular cycloadditions of indacenoditetracenes, antiaromatic analogues of undecacene
on-surface synthesis
cycloadditions
indacenoditetracene
antiaromatics
cyclodehydrogenation
The formation of s-indaceno[1,2-b:5,6-b′]ditetracene and as-indaceno[2,3-b:6,7-b′]ditetracene containing indenofluorene cores from a common precursor has been achieved by a dehydrogenative surface-assisted cyclization on Au(111) and confirmed by bond-resolved non-contact atomic force microscopy. On-surface generated as-indaceno[2,3-b:6,7-b′]ditetracenes undergo fusion, which leads to T-shaped adducts by an intermolecular cycloaddition. The same type of cycloaddition, which has no parallel in solution chemistry, has been observed between as-indaceno[2,3-b:6,7-b′]ditetracene and pentacene or octacene. These examples of surface-assisted cycloaddition provide perspectives for the rational design and synthesis of molecular nanostructures.
cris.lastimport.wos | 2024-04-09T20:49:12Z | |
dc.abstract.en | The formation of s-indaceno[1,2-b:5,6-b′]ditetracene and as-indaceno[2,3-b:6,7-b′]ditetracene containing indenofluorene cores from a common precursor has been achieved by a dehydrogenative surface-assisted cyclization on Au(111) and confirmed by bond-resolved non-contact atomic force microscopy. On-surface generated as-indaceno[2,3-b:6,7-b′]ditetracenes undergo fusion, which leads to T-shaped adducts by an intermolecular cycloaddition. The same type of cycloaddition, which has no parallel in solution chemistry, has been observed between as-indaceno[2,3-b:6,7-b′]ditetracene and pentacene or octacene. These examples of surface-assisted cycloaddition provide perspectives for the rational design and synthesis of molecular nanostructures. | pl |
dc.affiliation | Wydział Fizyki, Astronomii i Informatyki Stosowanej : Instytut Fizyki im. Mariana Smoluchowskiego | pl |
dc.contributor.author | Zuzak, Rafał - 200435 | pl |
dc.contributor.author | Stoica, Otilia | pl |
dc.contributor.author | Blieck, Rémi | pl |
dc.contributor.author | Echavarren, Antonio M. | pl |
dc.contributor.author | Godlewski, Szymon - 140233 | pl |
dc.date.accessioned | 2021-03-09T07:49:26Z | |
dc.date.available | 2021-03-09T07:49:26Z | |
dc.date.issued | 2021 | pl |
dc.description.number | 1 | pl |
dc.description.physical | 1548-1554 | pl |
dc.description.volume | 15 | pl |
dc.identifier.doi | 10.1021/acsnano.0c08995 | pl |
dc.identifier.eissn | 1936-086X | pl |
dc.identifier.issn | 1936-0851 | pl |
dc.identifier.project | ROD UJ / O | pl |
dc.identifier.uri | https://ruj.uj.edu.pl/xmlui/handle/item/266824 | |
dc.language | eng | pl |
dc.language.container | eng | pl |
dc.rights | Dodaję tylko opis bibliograficzny | * |
dc.rights.licence | bez licencji | |
dc.rights.uri | * | |
dc.subject.en | on-surface synthesis | pl |
dc.subject.en | cycloadditions | pl |
dc.subject.en | indacenoditetracene | pl |
dc.subject.en | antiaromatics | pl |
dc.subject.en | cyclodehydrogenation | pl |
dc.subtype | Article | pl |
dc.title | On-surface synthesis and intermolecular cycloadditions of indacenoditetracenes, antiaromatic analogues of undecacene | pl |
dc.title.journal | ACS Nano | pl |
dc.type | JournalArticle | pl |
dspace.entity.type | Publication |