Skeletal vibrations in CoZSM-5 affected by adsorbed molecules and reduction/oxidation of Co species

2008
journal article
article
cris.lastimport.scopus2024-04-24T02:56:30Z
cris.lastimport.wos2024-04-09T21:21:24Z
dc.abstract.enThe interaction of adsorbed probe molecules with $Co^{2+}$ cations in exchange position were investigated in the skeletal transmission window region. The position of the band of oxygen ring perturbed by $Co^{2+}$ provides information on the electron-acceptor properties of cation as well as the strength of interaction of cation with framework oxygens and with adsorbed molecules. The interaction of $Co^{2+}$ with CO, NO, $H_{2}O$, ammonia, acetylene, ethene, benzene and formaldehyde was investigated. The role of σ donation and π back donation in the interaction of CO and organic molecules was discussed.pl
dc.affiliationWydział Chemii : Zakład Chemii Nieorganicznejpl
dc.contributor.authorGóra-Marek, Kinga - 128133 pl
dc.date.accessioned2015-09-24T07:24:50Z
dc.date.available2015-09-24T07:24:50Z
dc.date.issued2008pl
dc.description.number1-3pl
dc.description.physical331-335pl
dc.description.volume892pl
dc.identifier.doi10.1016/j.molstruc.2008.05.049pl
dc.identifier.eissn1872-8014pl
dc.identifier.issn0022-2860pl
dc.identifier.urihttp://ruj.uj.edu.pl/xmlui/handle/item/15777
dc.languageengpl
dc.language.containerengpl
dc.rightsDodaję tylko opis bibliograficzny*
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dc.subject.enIR spectroscopypl
dc.subject.enzeolite CoZSM-5pl
dc.subject.enskeletal vibrationspl
dc.subtypeArticlepl
dc.titleSkeletal vibrations in CoZSM-5 affected by adsorbed molecules and reduction/oxidation of Co speciespl
dc.title.journalJournal of Molecular Structurepl
dc.typeJournalArticlepl
dspace.entity.typePublication

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