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Biomimetic direct aldol reaction of pyruvate esters with chiral aldehydes
Journal
Advanced Synthesis & Catalysis
45
Author
El-Sepelgy Osama
Młynarski Jacek
Volume
355
Issue
2-3
Pages
281-286
ISSN
1615-4150
eISSN
1615-4169
Language
English
Container language
English
Abstract in English
Direct aldol reactions of pyruvate esters with sugar aldehydes is efficiently promoted by dinuclear metal complexes or chiral Cinchona alkaloid organocatalysts. Application of sterically hindered aryl esters enables the to-date problematic aldol reaction of pyruvate donors with syn- or anti-selectivity en route to the short and efficient synthesis of 3-deoxy-2-ulosonic acids.
Affiliation
Wydział Chemii : Zakład Chemii Organicznej
Scopus© citations
10
| cris.lastimport.scopus | 2024-04-07T15:24:43Z | |
| cris.lastimport.wos | 2024-04-10T03:13:34Z | |
| dc.abstract.en | Direct aldol reactions of pyruvate esters with sugar aldehydes is efficiently promoted by dinuclear metal complexes or chiral Cinchona alkaloid organocatalysts. Application of sterically hindered aryl esters enables the to-date problematic aldol reaction of pyruvate donors with syn- or anti-selectivity en route to the short and efficient synthesis of 3-deoxy-2-ulosonic acids. | pl |
| dc.affiliation | Wydział Chemii : Zakład Chemii Organicznej | pl |
| dc.contributor.author | El-Sepelgy, Osama - 186330 | pl |
| dc.contributor.author | Młynarski, Jacek - 173385 | pl |
| dc.date.accessioned | 2015-06-18T06:57:54Z | |
| dc.date.available | 2015-06-18T06:57:54Z | |
| dc.date.issued | 2013 | pl |
| dc.description.number | 2-3 | pl |
| dc.description.physical | 281-286 | pl |
| dc.description.volume | 355 | pl |
| dc.identifier.doi | 10.1002/adsc.201200914 | pl |
| dc.identifier.eissn | 1615-4169 | pl |
| dc.identifier.issn | 1615-4150 | pl |
| dc.identifier.uri | http://ruj.uj.edu.pl/xmlui/handle/item/9749 | |
| dc.language | eng | pl |
| dc.language.container | eng | pl |
| dc.rights.licence | bez licencji | |
| dc.subtype | Article | pl |
| dc.title | Biomimetic direct aldol reaction of pyruvate esters with chiral aldehydes | pl |
| dc.title.journal | Advanced Synthesis & Catalysis | pl |
| dc.type | JournalArticle | pl |
| dspace.entity.type | Publication |
Affiliations
Wydział Chemii
Młynarski, Jacek
El-Sepelgy, Osama