The nanometric copper doped Ce1 - xCuxO2 - delta materials were obtained using a modified reverse nanoemulsion method followed by a previously optimized calcination. XRD patterns confirmed the presence of only one, fluorite-like CeO2 phase, within the range of 0 < x < 0.12, in accordance with embedding Cu ions in the CeO2 phase. High increase of catalytic activity in oxidative incineration of volatile organic compounds (VOCs) with Cu-doping was observed, equally with a high increase in the ionic conductivity related to the increase of concentration of oxygen vacancies in the ceria lattice. The impedance spectroscopy allowed to specify that the high catalytic activity of Ce1 - xCuxO2 (-) (delta) is bounded also with change of the share in ionic and electronic conductivities. Though, the active catalyst should reveal mixed ionic and electronic conductivities (MIEC), the higher share of ionic component of electrical conductivity seems to be essential. Such a conclusion is in accordance with the Mars-van Krevellen model of catalytic oxidation of VOC molecules.