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Effective catalytic disproportionation of aqueous
The two novel manganese( II ) complexes with 2-hydroxymethylpyridine (2-CH 2 OHpy) {[Mn 2 ( μ -Cl) 2
(2-CH 2 OHpy) 4 ]Cl 2 ·2H 2 O( 1 )} and 2-hydroxyethylpyridine (2-(CH 2 ) 2 OHpy) {Mn(2-(CH 2 ) 2 OHpy) 2 (NCS) 2 } were synthesized and characterized by means of X-ray di ff raction, IR, EPR, HF EPR spectroscopy, mag- netic and TG/DTG data. The complexes show catalase-like activity in neutral aqueous solution since they were able to disproportionate H_{2}O_{2} to harmless H_{2}O and O_{2} . Both complexes act as true catalysts since they reverted to their original form after depleting all the H_{2}O_{2} , as suggested by the operando resonant inelastic X-ray spectroscopy (RIXS) measurements.
cris.lastimport.scopus | 2024-04-24T03:19:43Z | |
cris.lastimport.wos | 2024-04-09T20:04:53Z | |
dc.abstract.en | The two novel manganese( II ) complexes with 2-hydroxymethylpyridine (2-CH 2 OHpy) {[Mn 2 ( μ -Cl) 2 - (2-CH 2 OHpy) 4 ]Cl 2 ·2H 2 O( 1 )} and 2-hydroxyethylpyridine (2-(CH 2 ) 2 OHpy) {[Mn(2-(CH 2 ) 2 OHpy) 2 (NCS) 2 ]( 2 )} were synthesized and characterized by means of X-ray di ff raction, IR, EPR, HF EPR spectroscopy, mag- netic and TG/DTG data. The complexes show catalase-like activity in neutral aqueous solution since they were able to disproportionate H_{2}O_{2} to harmless H_{2}O and O_{2} . Both complexes act as true catalysts since they reverted to their original form after depleting all the H_{2}O_{2} , as suggested by the operando resonant inelastic X-ray spectroscopy (RIXS) measurements. | pl |
dc.affiliation | Wydział Chemii : Zakład Krystalochemii i Krystalofizyki | pl |
dc.contributor.author | Zienkiewicz, Małgorzata | pl |
dc.contributor.author | Jabłońska-Wawrzycka, Agnieszka | pl |
dc.contributor.author | Szlachetko, Jakub | pl |
dc.contributor.author | Kayser, Yves | pl |
dc.contributor.author | Stadnicka, Katarzyna - 132048 | pl |
dc.contributor.author | Sawka-Dobrowolska, Wanda | pl |
dc.contributor.author | Jezierska, Julia | pl |
dc.contributor.author | Barszcz, Barbara | pl |
dc.contributor.author | Sá, Jacinto | pl |
dc.date.accessioned | 2015-06-02T12:43:10Z | |
dc.date.available | 2015-06-02T12:43:10Z | |
dc.date.issued | 2014 | pl |
dc.description.admin | [AB] Stadnicka, Katarzyna [SAP11004149] 50000141 | pl |
dc.description.number | 23 | pl |
dc.description.physical | 8599-8608 | pl |
dc.description.points | 40 | pl |
dc.description.volume | 43 | pl |
dc.identifier.doi | 10.1039/C3DT53288G | pl |
dc.identifier.eissn | 1477-9234 | pl |
dc.identifier.issn | 1477-9226 | pl |
dc.identifier.uri | http://ruj.uj.edu.pl/xmlui/handle/item/8722 | |
dc.language | eng | pl |
dc.language.container | eng | pl |
dc.rights.licence | bez licencji | |
dc.subtype | Article | pl |
dc.title | Effective catalytic disproportionation of aqueous $H_2O_2$ with di- and mono-nuclear manganese (II) complexes containing pyridine alcohols ligands | pl |
dc.title.journal | Dalton Transactions | pl |
dc.type | JournalArticle | pl |
dspace.entity.type | Publication |