Molecular theory of proper ferroelectricity in bent-core liquid crystals

2014
journal article
article
16
dc.abstract.enAntiferro- and ferro-electric ordering has been discovered in orthogonal smectic phases composed of nonchiral bent-core molecules. These systems are the only proper fluid ferroelectrics confirmed experimentally so far. We consider a molecular theory of proper ferroelectric ordering in isotropic, nematic and smectic A phases and conclude that the delicate balance between the tendencies for local parallel and antiparallel ordering of molecular electric and steric dipoles is strongly shifted in restricted geometries. This is a reason why dipolar ordering is more likely to occur within a smectic layer. We derive model interaction potentials for polar bent-core molecules and present the results of the mean-field theory of ferroelectric ordering in the orthogonal smectic phase taking into account also the molecular biaxiality. Order parameter profiles have been calculated numerically and phase diagrams are presented which enable one to analyze the relative importance of dipole-dipole interaction and intermolecular attraction modulated by polar bent-core molecular shape.pl
dc.contributor.authorOsipov, Mikhail A.pl
dc.contributor.authorPająk, Grzegorz - 200615 pl
dc.date.accessioned2017-04-05T14:30:25Z
dc.date.available2017-04-05T14:30:25Z
dc.date.issued2014pl
dc.date.openaccess0
dc.description.accesstimew momencie opublikowania
dc.description.number9pl
dc.description.versionostateczna wersja wydawcy
dc.description.volume37pl
dc.identifier.articleid79pl
dc.identifier.doi10.1140/epje/i2014-14079-0pl
dc.identifier.eissn1292-895Xpl
dc.identifier.issn1292-8941pl
dc.identifier.urihttp://ruj.uj.edu.pl/xmlui/handle/item/39330
dc.languageengpl
dc.language.containerengpl
dc.rightsDodaję tylko opis bibliograficzny*
dc.rights.licenceCC-BY
dc.rights.uri*
dc.share.typeinne
dc.subject.ensoft matter : liquid crystalspl
dc.subtypeArticlepl
dc.titleMolecular theory of proper ferroelectricity in bent-core liquid crystalspl
dc.title.journalThe European Physical Journal. E, Soft Matter and Biological Physicspl
dc.typeJournalArticlepl
dspace.entity.typePublication
dc.abstract.enpl
Antiferro- and ferro-electric ordering has been discovered in orthogonal smectic phases composed of nonchiral bent-core molecules. These systems are the only proper fluid ferroelectrics confirmed experimentally so far. We consider a molecular theory of proper ferroelectric ordering in isotropic, nematic and smectic A phases and conclude that the delicate balance between the tendencies for local parallel and antiparallel ordering of molecular electric and steric dipoles is strongly shifted in restricted geometries. This is a reason why dipolar ordering is more likely to occur within a smectic layer. We derive model interaction potentials for polar bent-core molecules and present the results of the mean-field theory of ferroelectric ordering in the orthogonal smectic phase taking into account also the molecular biaxiality. Order parameter profiles have been calculated numerically and phase diagrams are presented which enable one to analyze the relative importance of dipole-dipole interaction and intermolecular attraction modulated by polar bent-core molecular shape.
dc.contributor.authorpl
Osipov, Mikhail A.
dc.contributor.authorpl
Pająk, Grzegorz - 200615
dc.date.accessioned
2017-04-05T14:30:25Z
dc.date.available
2017-04-05T14:30:25Z
dc.date.issuedpl
2014
dc.date.openaccess
0
dc.description.accesstime
w momencie opublikowania
dc.description.numberpl
9
dc.description.version
ostateczna wersja wydawcy
dc.description.volumepl
37
dc.identifier.articleidpl
79
dc.identifier.doipl
10.1140/epje/i2014-14079-0
dc.identifier.eissnpl
1292-895X
dc.identifier.issnpl
1292-8941
dc.identifier.uri
http://ruj.uj.edu.pl/xmlui/handle/item/39330
dc.languagepl
eng
dc.language.containerpl
eng
dc.rights*
Dodaję tylko opis bibliograficzny
dc.rights.licence
CC-BY
dc.rights.uri*
dc.share.type
inne
dc.subject.enpl
soft matter : liquid crystals
dc.subtypepl
Article
dc.titlepl
Molecular theory of proper ferroelectricity in bent-core liquid crystals
dc.title.journalpl
The European Physical Journal. E, Soft Matter and Biological Physics
dc.typepl
JournalArticle
dspace.entity.type
Publication
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