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Enforcing multifunctionality : a pressure-induced spin-crossover photomagnet
Photomagnetic compounds are usually achieved by assembling preorganized individual molecules into rationally designed molecular architectures via the bottom-up approach. Here we show that a magnetic response to light can also be enforced in a nonphotomagnetic compound by applying mechanical stress. The nonphotomagnetic cyano-bridged FeII–NbIV coordination polymer {[FeII(pyrazole)4]2[NbIV(CN)8]·4H2O}n (FeNb) has been subjected to high-pressure structural, magnetic and photomagnetic studies at low temperature, which revealed a wide spectrum of pressure-related functionalities including the light-induced magnetization. The multifunctionality of FeNb is compared with a simple structural and magnetic pressure response of its analog {[MnII(pyrazole)4]2[NbIV(CN)8]·4H2O}n (MnNb). The FeNb coordination polymer is the first pressure-induced spin-crossover photomagnet.
cris.lastimport.wos | 2024-04-09T18:07:21Z | |
dc.abstract.en | Photomagnetic compounds are usually achieved by assembling preorganized individual molecules into rationally designed molecular architectures via the bottom-up approach. Here we show that a magnetic response to light can also be enforced in a nonphotomagnetic compound by applying mechanical stress. The nonphotomagnetic cyano-bridged FeII–NbIV coordination polymer {[FeII(pyrazole)4]2[NbIV(CN)8]·4H2O}n (FeNb) has been subjected to high-pressure structural, magnetic and photomagnetic studies at low temperature, which revealed a wide spectrum of pressure-related functionalities including the light-induced magnetization. The multifunctionality of FeNb is compared with a simple structural and magnetic pressure response of its analog {[MnII(pyrazole)4]2[NbIV(CN)8]·4H2O}n (MnNb). The FeNb coordination polymer is the first pressure-induced spin-crossover photomagnet. | pl |
dc.affiliation | Wydział Chemii : Zakład Chemii Nieorganicznej | pl |
dc.affiliation | Wydział Fizyki, Astronomii i Informatyki Stosowanej : Instytut Fizyki im. Mariana Smoluchowskiego | pl |
dc.contributor.author | Pinkowicz, Dawid - 126341 | pl |
dc.contributor.author | Rams, Michał - 100567 | pl |
dc.contributor.author | Mišek, Martin | pl |
dc.contributor.author | Kamenev, Konstantin V. | pl |
dc.contributor.author | Tomkowiak, Hanna | pl |
dc.contributor.author | Katrusiak, Andrzej | pl |
dc.contributor.author | Sieklucka, Barbara - 131848 | pl |
dc.date.accessioned | 2015-12-09T09:59:24Z | |
dc.date.available | 2015-12-09T09:59:24Z | |
dc.date.issued | 2015 | pl |
dc.date.openaccess | 0 | |
dc.description.accesstime | w momencie opublikowania | |
dc.description.number | 27 | pl |
dc.description.physical | 8795-8802 | pl |
dc.description.publication | 0,5 | pl |
dc.description.version | ostateczna wersja wydawcy | |
dc.description.volume | 137 | pl |
dc.identifier.doi | 10.1021/jacs.5b04303 | pl |
dc.identifier.eissn | 1520-5126 | pl |
dc.identifier.issn | 0002-7863 | pl |
dc.identifier.uri | http://ruj.uj.edu.pl/xmlui/handle/item/17917 | |
dc.language | eng | pl |
dc.language.container | eng | pl |
dc.rights | Dodaję tylko opis bibliograficzny | * |
dc.rights.licence | OTHER | |
dc.rights.uri | * | |
dc.share.type | inne | |
dc.subtype | Article | pl |
dc.title | Enforcing multifunctionality : a pressure-induced spin-crossover photomagnet | pl |
dc.title.journal | Journal of the American Chemical Society | pl |
dc.type | JournalArticle | pl |
dspace.entity.type | Publication |