$Fe^{II}$ spin-crossover phenomenon in the pentadecanuclear $\{Fe_9[Re(CN)_8]_6\}$  spherical cluster

Chorąży, Szymon; Podgajny, Robert; Nakabayashi, Koji; Stanek, Jan; Rams, Michał; Sieklucka, Barbara; Ohkoshi, Shin-ichi

doi:10.1002/anie.201500288

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spin-crossover phenomenon in the pentadecanuclear spherical cluster

2015

journal article

article

10.1002/anie.201500288

Journal

Angewandte Chemie. International Edition

45

Author

Chorąży Szymon

Podgajny Robert

Nakabayashi Koji

Stanek Jan

Rams Michał

Sieklucka Barbara

Ohkoshi Shin-ichi

Volume

54

Issue

17

Pages

5093-5097

ISSN

1433-7851

eISSN

1521-3773

Keywords in English

clusterverbindungen

cyanidliganden

eisen

rhenium

spin-crossover

Language

English

Container language

English

Abstract in English

The self-assembly of iron(II) ions with rare octacyanidorhenate(V) metalloligands in a methanolic solution results in the formation of a nanometric pentadecanuclear (1) molecule with a six-capped body-centered cubic topology. The cluster demonstrates a thermally-induced spin-crossover phase transition at which occurs selectively for a single ion embedded in the center of a cluster core.

dc.abstract.en	The self-assembly of iron(II) ions with rare octacyanidorhenate(V) metalloligands in a methanolic solution results in the formation of a nanometric pentadecanuclear $\{ Fe^{II}_{9}[Re^{V}(CN)_{8}]_{6}(MeOH)_{24}\}⋅10 MeOH$ (1) molecule with a six-capped body-centered cubic topology. The cluster demonstrates a thermally-induced spin-crossover phase transition at $T_{1/2}=195 K$ which occurs selectively for a single $Fe^{II}$ ion embedded in the center of a cluster core.	pl
dc.affiliation	Wydział Fizyki, Astronomii i Informatyki Stosowanej : Instytut Fizyki im. Mariana Smoluchowskiego	pl
dc.affiliation	Wydział Chemii : Zakład Chemii Nieorganicznej	pl
dc.contributor.author	Chorąży, Szymon - 107013	pl
dc.contributor.author	Podgajny, Robert - 131465	pl
dc.contributor.author	Nakabayashi, Koji	pl
dc.contributor.author	Stanek, Jan - 100112	pl
dc.contributor.author	Rams, Michał - 100567	pl
dc.contributor.author	Sieklucka, Barbara - 131848	pl
dc.contributor.author	Ohkoshi, Shin-ichi	pl
dc.date.accessioned	2015-07-18T09:19:49Z
dc.date.available	2015-07-18T09:19:49Z
dc.date.issued	2015	pl
dc.description.number	17	pl
dc.description.physical	5093-5097	pl
dc.description.volume	54	pl
dc.identifier.doi	10.1002/anie.201500288	pl
dc.identifier.eissn	1521-3773	pl
dc.identifier.issn	1433-7851	pl
dc.identifier.uri	http://ruj.uj.edu.pl/xmlui/handle/item/13324
dc.language	eng	pl
dc.language.container	eng	pl
dc.rights	Dodaję tylko opis bibliograficzny	*
dc.rights.licence	bez licencji
dc.rights.uri		*
dc.subject.en	clusterverbindungen	pl
dc.subject.en	cyanidliganden	pl
dc.subject.en	eisen	pl
dc.subject.en	rhenium	pl
dc.subject.en	spin-crossover	pl
dc.subtype	Article	pl
dc.title	$Fe^{II}$ spin-crossover phenomenon in the pentadecanuclear $\{Fe_9[Re(CN)_8]_6\}$ spherical cluster	pl
dc.title.journal	Angewandte Chemie. International Edition	pl
dc.type	JournalArticle	pl
dspace.entity.type	Publication

Affiliations

Wydział Fizyki, Astronomii i Informatyki Stosowanej

Stanek, Jan

Rams, Michał

Wydział Chemii

Podgajny, Robert

Sieklucka, Barbara

Chorąży, Szymon

No affiliation

Nakabayashi, Koji

Ohkoshi, Shin-ichi

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