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A novel single-site manganese(II) complex of a pyridine derivative as a catalase mimetic for disproportionation of
Author
Zienkiewicz Małgorzata
Szlachetko Jakub
Lothschütz Christian
Hodorowicz Maciej
Jabłońska-Wawrzycka Agnieszka
Barszcz Barbara
Sá Jacinto
Volume
42
Issue
21
Pages
7761-7767
ISSN
1477-9226
eISSN
1477-9234
Language
English
Container language
English
Abstract in English
A novel single site Mn( II ) complex was successfully synthesized and tested in the aqueous disproportiona- tion of hydrogen peroxide. The complex was found to be stable (HR-XAS) and exhibits catalase-like activity in neutral pH. Theoretical calculations suggested a reaction mechanism involving two complexes, changes in metal oxidation state and proton shuttling.
Affiliation
Wydział Chemii : Zakład Chemii Nieorganicznej
| cris.lastimport.scopus | 2024-04-24T04:32:47Z | |
| cris.lastimport.wos | 2024-04-09T18:49:09Z | |
| dc.abstract.en | A novel single site Mn( II ) complex was successfully synthesized and tested in the aqueous disproportiona- tion of hydrogen peroxide. The complex was found to be stable (HR-XAS) and exhibits catalase-like activity in neutral pH. Theoretical calculations suggested a reaction mechanism involving two complexes, changes in metal oxidation state and proton shuttling. | pl |
| dc.affiliation | Wydział Chemii : Zakład Chemii Nieorganicznej | pl |
| dc.contributor.author | Zienkiewicz, Małgorzata | pl |
| dc.contributor.author | Szlachetko, Jakub | pl |
| dc.contributor.author | Lothschütz, Christian | pl |
| dc.contributor.author | Hodorowicz, Maciej - 128328 | pl |
| dc.contributor.author | Jabłońska-Wawrzycka, Agnieszka | pl |
| dc.contributor.author | Barszcz, Barbara | pl |
| dc.contributor.author | Sá, Jacinto | pl |
| dc.date.accessioned | 2015-06-23T11:21:33Z | |
| dc.date.available | 2015-06-23T11:21:33Z | |
| dc.date.issued | 2013 | pl |
| dc.description.number | 21 | pl |
| dc.description.physical | 7761-7767 | pl |
| dc.description.volume | 42 | pl |
| dc.identifier.doi | 10.1039/C3DT50288K | pl |
| dc.identifier.eissn | 1477-9234 | pl |
| dc.identifier.issn | 1477-9226 | pl |
| dc.identifier.uri | http://ruj.uj.edu.pl/xmlui/handle/item/10113 | |
| dc.language | eng | pl |
| dc.language.container | eng | pl |
| dc.rights.licence | bez licencji | |
| dc.subtype | Article | pl |
| dc.title | A novel single-site manganese(II) complex of a pyridine derivative as a catalase mimetic for disproportionation of $H_2O_2$ in water | pl |
| dc.title.journal | Dalton Transactions | pl |
| dc.type | JournalArticle | pl |
| dspace.entity.type | Publication |